The allylperoxyl radical derived from 1-(cyclohex-1-enyl)cyclohexyl hydroperoxide does not undergo allylic rearrangement, but in the presence of oxygen it undergoes autoxidation with an intramolecular propagation step, leading to the formation of 1-(6-hydroperoxycyclohex-1-enyl)cyclohexyl hydroperoxide.
A. G. Davies, I. G. E. Davison and C. H. Schiesser, J. Chem. Soc., Chem. Commun., 1989, 742 DOI: 10.1039/C39890000742
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