The disc-like compounds, 5,6,5′,6′,5″,6″,5‴,6‴-octadodecyltetrapyrazino[2,3-b:2′,3′-g:2″,3″-I:2‴,3‴-q]porphyrazine (C12PzH2) and the copper(II) complex (C12PzCu), which have now been synthesized, exhibit different columnar mesomorphism (Dhd for C12PzH2, Drd for C12PzCu).
K. Ohta, T. Watanabe, T. Fujimoto and I. Yamamoto, J. Chem. Soc., Chem. Commun., 1989, 1611 DOI: 10.1039/C39890001611
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