Aryl(methylene)oxyl radicals generated by decarboxylation of the thiohydroxamate ester (8) undergo 6-endo cyclisation, yielding ketones (9) and (11), mimicking an unusual biosynthetic conversion.
S. A. Ahmad-Junan, A. J. Walkington and D. A. Whiting, J. Chem. Soc., Chem. Commun., 1989, 1613 DOI: 10.1039/C39890001613
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