Thermal or frictional initiation of mixtures of MCI4(I)(M = Ti,V)and Li3N or Li2O produce MN,TixVy,N or MO2via a rapid, exothermic, solid–liquid metathesis reaction.
A. Hector and I. P. Parkin, J. Chem. Soc., Chem. Commun., 1993, 1095 DOI: 10.1039/C39930001095
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