The complexation of copper(II/I) and silver(II/I) in a phenanthroline capped porphyrin ligand has been studied and shows the formation of mixed valence homodinuclear complexes together with a kinetically enhanced complexation within the porphyrin core.
A. Giraudeau, J. P. Gisselbrecht, M. Gross and J. Weiss, J. Chem. Soc., Chem. Commun., 1993, 1103 DOI: 10.1039/C39930001103
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