Issue 19, 1993

Dalton communications. Unusual magnetic and structural one-dimensional nickel(II) azido systems

Abstract

The complexes of general formula [Ni(L)(N3)][ClO4](L is meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane or 2,3-dimethyl-1,4,8,11-tetraazacyclotetradeca-1,3-diene), have been characterized by X-ray crystallography; both are chains in which the nickel(II)–tetraammine fragment is bridged by one µ-azido ligand in trans arrangement, showing unusual magnetic and/or crystallographic properties; preliminary magnetic susceptibility data indicate strong antiferromagnetic coupling.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1993, 2975-2976

Dalton communications. Unusual magnetic and structural one-dimensional nickel(II) azido systems

A. Escuer, R. Vicente, M. S. E. Fallah, J. Ribas, X. Solans and M. Font-Bardía, J. Chem. Soc., Dalton Trans., 1993, 2975 DOI: 10.1039/DT9930002975

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