Arene oxides of naphthalene, quinoline, triphenylene, benzo[e]pyrene, and dibenz[a,c]anthracene have been synthesised in enantiopure (1a–c) or racemic form (1d–f), free from oxepine isomers (3d–f) from cis-diol precursors (7a–f)via chloroacetate (9a–f) or dimesylate (13a) intermediates.
D. R. Boyd, N. D. Sharma, R. Agarwal, N. A. Kerley, R. A. S. McMordie, A. Smith, H. Dalton, A. J. Blacker and G. N. Sheldrake, J. Chem. Soc., Chem. Commun., 1994, 1693 DOI: 10.1039/C39940001693
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