Room-temperature treatment of Mo(NAr)2(OBut)21(Ar = 2,6-Pri2C6H3) with excess PhNCO in pentane affords the bis(carbamate) complex, Mo(NAr)2[NPhC(O)OBut]22, as a result of isocyanate insertion into both of the metal–alkoxide bonds; contrastingly 1 adds PhNCS to one metal–nitrogen bond to give the thioureato-N,N′ complex Mo(NAr)[NPhC(S)NAr](OBut)23.
V. C. Gibson, C. Redshaw, W. Clegg and M. R. J. Elsegood, J. Chem. Soc., Chem. Commun., 1994, 2635 DOI: 10.1039/C39940002635
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