Issue 4, 1994
From the journal:

Journal of the Chemical Society, Dalton Transactions

Monocyclooctatetraene uranium thiolate complexes. Crystal structure of [{U(η-C8H8)(µ-SPri)2}2]

Pascal C. Leverd,   Thérèse Arliguie,   Monique Lance,   Martine Nierlich,   Julien Vigner  and  Michel Ephritikhine  

Abstract

The monocyclooctatetraene uranium bis(thiolate) complexes [U(cot)(SR)2](cot =η-C8H8, R = Bun or Pri) were prepared by treating [U(cot)(BH4)2]1 with the corresponding thiol or NaSR reagent. The isopropane thiolate derivative is a dimer in the crystalline form, with four bridging SPri ligands, and this structure is retained in solution. Reaction of 1 with NaSBut afforded the anion [U(cot)(SBut)3]– which adopts a three-legged piano-stool configuration.

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Article information

DOI
https://doi.org/10.1039/DT9940000501
Article type
Paper

J. Chem. Soc., Dalton Trans., 1994, 501-504

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Monocyclooctatetraene uranium thiolate complexes. Crystal structure of [{U(η-C8H8)(µ-SPri)2}2]

P. C. Leverd, T. Arliguie, M. Lance, M. Nierlich, J. Vigner and M. Ephritikhine, J. Chem. Soc., Dalton Trans., 1994, 501 DOI: 10.1039/DT9940000501

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