Diastereoselective epoxidation of allylic phosphine oxides
Abstract
Allylic phosphine oxides are epoxidised anti selectively by m-CPBA, but this selectivity can be reversed if the allylic phosphine oxide is also an allylic alcohol.
Allylic phosphine oxides are epoxidised anti selectively by m-CPBA, but this selectivity can be reversed if the allylic phosphine oxide is also an allylic alcohol.
J. Clayden, E. W. Collington, E. Egert, A. B. McElroy and S. Warren, J. Chem. Soc., Perkin Trans. 1, 1994, 2801 DOI: 10.1039/P19940002801
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