Optical absorption and EPR studies on a six-coordinate iron(III)–tetramesitylporphyrin–hydrogen peroxide complex having a nitrogenous axial ligand
Abstract
The formation of a six-coordinate FeIII TMP–hydrogen peroxide complex (TMP = tetramesitylporphyrin), having a nitrogenous ligand at the axial position, is demonstrated by means of simultaneous EPR and optical absorption measurements at 77 K.