A perylenylethene 1 undergoes two-way isomerization through an adiabatic process in the triplet state on direct irradiation as well as on Michler's ketone sensitization.
T. Arai and O. Takahashi, J. Chem. Soc., Chem. Commun., 1995, 1837 DOI: 10.1039/C39950001837
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