Pseudopotential ab initio calculations on SAu3+ and S(AuPH3)3+ closely reproduce the experimental Au–S–Au angles of monomeric S(AuPR3)3+(PR3= PPh3, PPri3) if both correlation and relativistic effects are included.
P. Pyykkö, K. Angermaier, B. Assmann and H. Schmidbaur, J. Chem. Soc., Chem. Commun., 1995, 1889 DOI: 10.1039/C39950001889
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