ab initio Calculations as well as experimental results show that the C = S bond of a thioamide can act as a dienophile in the Diels–Alder reaction provided that the nitrogen atom is substituted by π-acceptor groups.
R. Arnaud, P. Y. Chavant, K. Molvinger and Y. Vallée, J. Chem. Soc., Chem. Commun., 1995, 1897 DOI: 10.1039/C39950001897
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