The nitro-aldehyde 6α/β readily cyclizes to form the A-ring of taxol in quantitative yield; further elaboration of the α,β-unsaturated nitro compound 12 gave the enone 16 and the 13α alcohol 17 respectively.
P. Magnus and P. Pye, J. Chem. Soc., Chem. Commun., 1995, 1933 DOI: 10.1039/C39950001933
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