Reaction of 1, 2-diaminoethane-N,N,N′,N′-tetra(N-rnethylacetamide) L with K2[PtCl4] in aqueous solution gave H2L[PtCl4] and the unexpected product cis-Pt(LH–2)Cl2 which is the first reported structure of a platinum(IV) complex containing deprotonated amide ligands and a model for platinum(IV)–peptide/protein interactions.
C. J. Campbell, A. Castineiras and K. B. Nolan, J. Chem. Soc., Chem. Commun., 1995, 1939 DOI: 10.1039/C39950001939
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