Issue 19, 1995

COS trapping by palladium pyrazolates: addition vs. clathration

Abstract

[{Pd(dmpz)2(Hdmpz)2}2](Hdmpz = 3,5-dimethylpyrazole) reacts with COS, both in solution and in the solid state, affording [Pd{SC(O)dmpz}2] and [{Pd(dmpz)2(Hdmpz)2}2]mdot;COS, respectively; the structure of the latter is determined by ab initio methods from conventional X-ray powder diffraction data only.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1995, 1955-1956

COS trapping by palladium pyrazolates: addition vs. clathration

N. Masciocchi, M. Moret, A. Sironi, G. A. Ardizzoia, S. Cenini and G. L. Monica, J. Chem. Soc., Chem. Commun., 1995, 1955 DOI: 10.1039/C39950001955

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