[Cl3Ga–NReCl2(PMe2Ph)3] and [Cl3Ga–NReCl(PMe2Ph)3(NCMe)][GaCl4]: the first complexes with nitrido bridges between main group and transition metals
Abstract
Almost linear nitrogen bridges between rhenium and gallium are formed during the reaction of rhenium(V) complexes containing terminal ‘N3–’ ligands with gallium trichloride.