Synthesis of two new antimony sulfide clusters: structures of [PPh4]2[Sb6S6] and [PPh4]2[Sb4S6]
Abstract
Two new anionic antimony sulfide clusters [Sb6S6]2– and [Sb4S6]2– have been prepared and structurally characterized from the reduction of Sb2S5 with BH4– and [FeH(CO)4]– respectively.