Dibutyltin polymers with much higher molecular weights(GPC, polystyrene standards: Mn=ca. 1 × 106) than previously reported are prepared by Wurtz coupling of Bu2SnCl2 monomer; the reaction conditions are critical in achieving the maximum chain length, as polymer degradation results from prolonged reaction times.
N. Devylder, M. Hill, K. C. Molloy and G. J. Price, Chem. Commun., 1996, 711 DOI: 10.1039/CC9960000711
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