Diazacoronand 2 undergoes drastic conformational switching upon binding sodium ions as demonstrated by solution- and solid-state studies, which permit the design of efficient fluorescent PET (photoinduced electron transfer) switches 3a,b.
A. P. de Silva, H. Q. N. Gunaratne, T. Gunnlaugsson and M. Nieuwenhuizen, Chem. Commun., 1996, 1967 DOI: 10.1039/CC9960001967
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