Osmium(ii) complexes of N-aryl-1,2-arylene diimines formed viaortho-dimerization of ArNH2: synthesis, structure and redox properties
Abstract
A family of ortho-arylene diimine chelates,
[OsBr
2
L
2
] (L = N-aryl-1,2-arylene diimine),
which represent the first examples of osmium–quinonediimine
complexes, are isolated from the reaction of
[NH
4
]
2
[OsBr
6
] with aromatic amines,
ArNH
2
.
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