The crystal structure of Cl3Al–O–PCl3 contains covalent molecular units with an essentially linear Al–O–P axis, and a similar solution structure is indicated by NMR spectroscopy.
N. Burford, A. D. Phillips, R. W. Schurko, R. E. Wasylishen and J. F. Richardson, Chem. Commun., 1997, 2363 DOI: 10.1039/A705781D
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