A reversal of the stereochemistry of base mediated isomerisation of some isonitrile epoxides to hydroxy-vinyl isonitriles on changing from lithium diisopropylamide to lithium bis(trimethylsilyl)amide is reported and applied to a synthesis of racemic desepoxyaerocyanidin.
J. E. Baldwin, D. Chen and A. T. Russell, Chem. Commun., 1997, 2389 DOI: 10.1039/A706830A
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