A sterically protected diphosphinidenecyclobutene 5 bearing a bulky 2,4,6-triisopropylphenyl group is prepared and allowed to react with W(CO)5(thf) to give a doubly tungsten-coordinated complex 8, with chelate- and π-type coordination; the structure of the complex is confirmed by X-ray analysis.
M. Yoshifuji and Y. Ichikawa, Chem. Commun., 1998, 27 DOI: 10.1039/A706963D
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