Palladium-catalysed carbonyl allylations by mixed (E)- and (Z)-1,3-dichloropropene with SnI2–Bu4NI and SnCl2 diastereoselectively produce syn and anti 1-substituted 2-chlorobut-3-en-1-ols, respectively. These are transformed into cis and trans 1-substituted 2-vinyl epoxides.
Y. Masuyama, A. Ito and Y. Kurusu, Chem. Commun., 1998, 315 DOI: 10.1039/A707865J
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