An asymmetric disulfide linkage, formed by conjugation of a 5-nitropyridine-2-sulfenyl activated thioglycoside and a protein or pre-assembled peptide sequence, represents a good structural mimic of natural asparagine glycosylation.
W. M. Macindoe, A. H. van Oijen and G. Boons, Chem. Commun., 1998, 847 DOI: 10.1039/A708701B
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