The rigid, aromatic bis-tridentate bridging ligand tetrapyrido[2,3-a:3′,2′-c:2″,3″-h:3″′,2″′-j]phenazine (tpp) allowed the preparation of linear, stable bi- and tri-nuclear complexes of ruthenium(II) exhibiting low energy Ru → tpp MLCT absorptions and a strong electronic coupling in the mixed-valence state.
P. Bonhôte, A. Lecas and E. Amouyal, Chem. Commun., 1998, 885 DOI: 10.1039/A709013G
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