Lithium fluoride formed in situ is trapped by [TiF3(C5Me5)]2: an equilibrium with cleavage of a Ti–F–Ti bond and a model compound for molecular lithium fluoride
Abstract
Synthesis and structure of [{(C5Me5)TiF3}4(LiF)] and its solution equilibrium involving cleavage of a titanium–fluorine–titanium bond is reported.