Chiral non-racemic acyloxypyrrolinones are converted into alkoxypyrrolinones with retention of configuration by a palladium catalyzed allylic substitution; this comprises a key step in a short chemo-enzymatic route to acyliminium ion precursors.
A. D. Cuiper and R. M. Kellogg, Chem. Commun., 1998, 655 DOI: 10.1039/A800444G
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