Solid state polymerization of the [1]ferrocenophane Fe(η-C5H4)2SiMePh yields a stereoregular poly(ferrocenylmethylphenylsilane), the first example of a stereoregular organometallic polymer.
J. Rasburn, D. A. Foucher, W. F. Reynolds and G. Julius Vancso, Chem. Commun., 1998, 843 DOI: 10.1039/A801042K
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