The new layer compound CsTa4S5(S2)(PS4)3 was synthesized by the reaction of Ta metal in polythiophosphate melts. Its structure is based on Ta4S5(S2) clusters which are condensed by PS43– groups.
V. Derstroff and W. Tremel, Chem. Commun., 1998, 913 DOI: 10.1039/A801155I
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