A porphyrin with two fullerene substituents is prepared by condensation of a C60 aldehyde derivative and dipyrrol-2-yl methane and by reaction of a preconstructed porphyrin with C60 itself; it is obtained as a mixture of two conformers in slow equilibrium, as shown by a variable temperature NMR study.
J. Nierengarten and J. Nicoud, Chem. Commun., 1998, 1545 DOI: 10.1039/A803434F
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