Large-ring sigmatropic migrations do not necessarily follow the ‘least motion principle’ and can only be rationalized by a combination of experimental and computational techniques.
I. D. Gridnev, Y. N. Bubnov, P. R. Schreiner, M. E. Gurskii, A. O. Krasavin and V. I. Mstislavski, Chem. Commun., 1998, 2507 DOI: 10.1039/A806201C
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