Issue 21, 1998

A long-lived 2E state for a Cr(III)N6 amine chromophore at 298 K: [Cr(fac-Me5-D3htricosaneN6)]Cl3

Abstract

The 2E state lifetime of the C3 ion [Cr(fac-Me5-D3htrico-saneN6)]3+ is 235 µs in H2O and 1.5 ms in D2O at 298 K, the longest lifetimes yet reported for a saturated Cr(III)N6 chromophore at room temperature.

Article information

Article type
Paper

Chem. Commun., 1998, 2291-2292

A long-lived 2E state for a Cr(III)N6 amine chromophore at 298 K: [Cr(fac-Me5-D3htricosaneN6)]Cl3

K. N. Brown, R. J. Geue, A. M. Sargeson, G. Moran, S. F. Ralph and H. Riesen, Chem. Commun., 1998, 2291 DOI: 10.1039/A806321D

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