Issue 22, 1998
From the journal:

Chemical Communications

Novel elimination of hydroxylamine and formation of a nickel tetramer on reactions of glutarodihydroxamic acid with model dinickel hydrolases‡

David A. Brown,   Laurence P. Cuffe,   Noel J. Fitzpatrick,   William K. Glass,   Kara Herlihy,   Hassan Nimir,   Oliver Deeg,   William Errington  and  Terence J. Kemp  

Abstract

Reactions of glutarodihydroxamic acid with the hydrolase enzyme urease models, [Ni2(µ-H2O)(OAc)4(tmen)2] and [Ni2(OAc)3(urea)(tmen)2][OTf], lead to novel hydroxylamine elimination and formation of [Ni2(OAc)2{µ-O(N)(OC)2(CH2)3}(tmen)2][OTf] and the tetramer [Ni4(OAc)2(gluA2)2(tmen)4][OTf]2, respectively, both of which are structurally characterised by X-ray crystallography.

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Article information

DOI
https://doi.org/10.1039/A806911E
Article type
Paper

Chem. Commun., 1998, 2433-2434

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Novel elimination of hydroxylamine and formation of a nickel tetramer on reactions of glutarodihydroxamic acid with model dinickel hydrolases‡

D. A. Brown, L. P. Cuffe, N. J. Fitzpatrick, W. K. Glass, K. Herlihy, H. Nimir, O. Deeg, W. Errington and T. J. Kemp, Chem. Commun., 1998, 2433 DOI: 10.1039/A806911E

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