An amide macrocycle with a highly preorganised cavity containing both polar and non-polar recognition sites forms stable complexes with cyclic dipeptides in water via amide–amide hydrogen-bonds, NH–π hydrogen-bonds and hydrophobic contacts.
C. Allott, H. Adams, C. A. Hunter, J. A. Thomas, P. L. Bernad Jr. and C. Rotger, Chem. Commun., 1998, 2449 DOI: 10.1039/A807110A
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