The primary photochemical reactions of iron(III) either in the form of Fe(ClO4)3 or FeCl3 with phenol in aqueous solution have been studied by nanosecond laser photolysis (λ = 347 nm). The mechanism leads to the formation of phenoxyl radical PhO˙ and involves the photo-oxidation of phenol by Cl˙ and Cl2˙– radicals in the presence of added Cl– anion.
V. A. Nadtochenko and J. Kiwi, J. Chem. Soc., Perkin Trans. 2, 1998, 1303 DOI: 10.1039/A802022A
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