Two new covalently linked functional model compounds for the Fea3/CuB active sites of heme-copper oxidases have been prepared and characterized by novel synthetic methodologies; the X-ray structure of the Zn form and the electrocatalytic reduction of O2 by the Fe/Cu forms are reported.
J. P. Collman, R. Schwenninger, M. Rapta, M. Bröring and L. Fu, Chem. Commun., 1999, 137 DOI: 10.1039/A807598K
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