The first total synthesis of the title compound has been accomplished using an intramolecular Diels–Alder reaction of a masked o-benzoquinone, anionic [1,3]-rearrangement of a vinylbicyclo[2.2.2]octenol and intramolecular hetero-Michael addition of a hydroxy enone as the key steps.
W. Liu and C. Liao, Chem. Commun., 1999, 117 DOI: 10.1039/A808714H
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