The preparations of the first examples of homoleptic hexaseleno- and hexatelluro-ether complexes, [Ru{MeC(CH2EMe)3}2](CF3SO3)2 (E = Se or Te) are described; the crystal structure of the former shows both ligands binding facially to the RuII centre, with the Se-based lone pairs in the syn arrangement.
W. Levason, S. D. Orchard and G. Reid, Chem. Commun., 1999, 1071 DOI: 10.1039/A901930H
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