Issue 12, 1999
From the journal:

Chemical Communications

A homobimetallic vanadium d2–d2 complex (Cp2V)2(3η:4η-Me3SiC[triple bond, length half m-dash]C–C[double bond, length half m-dash]C–C[triple bond, length half m-dash]CSiMe3):structure and magnetism

Robert Choukroun,   Christian Lorber,   Bruno Donnadieu,   Bernard Henner,   Richard Frantz  and  Christian Guerin  

Abstract

The d2–d2 homobimetallic complex (Cp2V)2(3η:4η-Me3-SiC[triple bond, length half m-dash]C–C[double bond, length half m-dash]C–C[triple bond, length half m-dash]CSiMe3) was synthesized from Me3SiC[triple bond, length half m-dash]C–C[triple bond, length half m-dash]C–C[triple bond, length half m-dash]CSiMe3 and Cp2V and characterized by an X-ray crystal structure; magnetic moment measurements from 300 to 2 K indicated a weak antiferromagnetic J exchange coupling of –3.7 cm–1.

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Article information

DOI
https://doi.org/10.1039/A902370D
Article type
Paper

Chem. Commun., 1999, 1099-1100

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A homobimetallic vanadium d2–d2 complex (Cp2V)2(3η:4η-Me3SiC[triple bond, length half m-dash]C–C[double bond, length half m-dash]C–C[triple bond, length half m-dash]CSiMe3):structure and magnetism

R. Choukroun, C. Lorber, B. Donnadieu, B. Henner, R. Frantz and C. Guerin, Chem. Commun., 1999, 1099 DOI: 10.1039/A902370D

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