Two new oxovanadium borophosphates have been hydrothermally synthesized; they are structural analogues and are both constructed by [(VO)12{O3POB(O)2OPO3}6]18– 12-member ring clusters with NH4+ and K+ cations encapsulated in the rings, respectively; an extended network of hydrogen bonds between anions, cations and crystal water molecules link the structures in three dimensions.
Y. Zhao, G. Zhu, W. Liu, Y. Zou and W. Pang, Chem. Commun., 1999, 2219 DOI: 10.1039/A906668C
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