A γ-irradiated synthetic hydroxyapatite sample was studied by EPR and ENDOR. At room temperature the EPR spectra are composed of two species, both with axially symmetric -tensors (g⊥=2.0061 and g//=2.0018) and attributed to CO- radicals. One of these species presents a hyperfine structure with a nuclear spin I=1/2
D. U. Schramm and A. M. Rossi, Phys. Chem. Chem. Phys., 1999, 1, 2007 DOI: 10.1039/A900206E
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