Crystal structures of 1∶1 adducts of diborane(4) compounds and the electron acceptors TCNQ and TCNE, namely B2(1,2-E2C6H4)2·TCNQ (E = O or S) and B2(1,2-E2C6H4)2·TCNE (E = O or S), have been found to show predominantly two-dimensional heteromolecular packing motifs with a variety of interlayer packings.
T. B. Marder, N. C. Norman, A. Guy Orpen, M. J. Quayle and C. R. Rice, J. Chem. Soc., Dalton Trans., 1999, 2127 DOI: 10.1039/A901169B
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