Up to 40% ee was obtained in the asymmetric epoxidation of styrene and other unfunctionalised olefins catalysed by the ruthenium(II) complex [RuCl(PNNP)]PF6 (PNNP = N,N′-{(o-diphenylphosphino)benzylidene}-(1S,2S)-diiminocyclohexane)
using hydrogen peroxide as the primary oxidant.
R. M. Stoop and A. Mezzetti, Green Chem., 1999, 1, 39 DOI: 10.1039/A809640F
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