Issue 6, 2000
From the journal:

Chemical Communications

Radical-chain deoxygenation of tertiary alcohols, protected as their methoxymethyl (MOM) ethers, using thiols as polarity-reversal catalysts

Hai-Shan Dang,a   Paola Franchi†a  and  Brian P. Roberts*a  

* Corresponding authors

a Christopher Ingold Laboratories, Department of Chemistry, University College London, 20 Gordon Street, London, UK
E-mail: b.p.roberts@ucl.ac.uk

Abstract

The deoxygenation of tertiary alcohols can be accomplished by heating their MOM ethers in the presence of a peroxide initiator and a thiol catalyst: the proposed radical-chain mechanism is supported by EPR spectroscopic studies.

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Article information

DOI
https://doi.org/10.1039/B000533I
Article type
Communication
Submitted
19 Jan 2000
Accepted
14 Feb 2000
First published
09 Mar 2000

Chem. Commun., 2000, 499-500

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Radical-chain deoxygenation of tertiary alcohols, protected as their methoxymethyl (MOM) ethers, using thiols as polarity-reversal catalysts

H. Dang, P. Franchi and B. P. Roberts, Chem. Commun., 2000, 499 DOI: 10.1039/B000533I

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