The first examples of enantiomerically pure metallomesogens containing the chiral centre directly bonded to the metal are reported; the chiral complexes show different phase behaviour to the racemic modifications.
trans-Dichloro(stilbazole)(methyl n-alkyl sulfoxide)platinum(II) complexes: the first examples of metallomesogens containing chiral centres directly bonded to the metal
F. P. Fanizzi, V. Alicino, C. Cardellicchio, P. Tortorella and J. P. Rourke, Chem. Commun., 2000, 673 DOI: 10.1039/B000594K
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