Issue 8, 2000
From the journal:

Chemical Communications

Bis(pentafluorophenyl)boron azide: synthesis and structural characterization of the first dimeric boron azide

Wolfgang Fraenk,a   Thomas M. Klapötke,*a   Burkhard Krumma  and  Peter Mayera  

* Corresponding authors

a Department of Chemistry, Ludwig-Maximilians-University, Butenandtstr. 5-13 (D), D-81377, Munich, Germany.
E-mail: tmk@cup.uni-muenchen.de

Abstract

The reaction of (C6F5)2BCl with trimethylsilyl azide results in the formation of (C6F5)2BN3 1; evaporation of the stabilizing solvent results in irreversible dimerization yielding [(C6F5)2BN3]2 1a as the first example of a dimeric boron azide; in the presence of pyridine a stable adduct (C6F5)2BN3·py 2 is isolated.

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Article information

DOI
https://doi.org/10.1039/B001103G
Article type
Communication
Submitted
09 Feb 2000
Accepted
06 Mar 2000
First published
03 Apr 2000

Chem. Commun., 2000, 667-668

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Bis(pentafluorophenyl)boron azide: synthesis and structural characterization of the first dimeric boron azide

W. Fraenk, T. M. Klapötke, B. Krumm and P. Mayer, Chem. Commun., 2000, 667 DOI: 10.1039/B001103G

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