A new allylation reaction of carbonyl compounds using allenes is described; homoallylic alcohols were obtained in moderate to good yields from aryl iodides, allenes and carbonyl compounds and an excellent diastereoselection was exhibited when 2-hydroxycyclohexanone was employed.
Palladium–indium mediated Barbier-type allylation of aldehydes with allenes
U. Anwar, R. Grigg, M. Rasparini, V. Savic and V. Sridharan, Chem. Commun., 2000, 645 DOI: 10.1039/B001457P
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